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1.
Moisture-dependent transition from strong to weak hydrogen bonding in wood polysaccharides
Filip Majstorović, Jakub Michal Sandak, 2026, izvirni znanstveni članek

Opis: Near-infrared (NIR) spectroscopy combined with multivariate analysis was employed to investigate moisture- dependent hydrogen bonding of water in softwood cell walls. Spectral variations at equilibrium moisture con- tents were analyzed using principal component analysis and perturbation-correlation moving-window two- dimensional correlation spectroscopy to distinguish water populations with varying hydrogen-bond strengths. A distinct transition in hydrogen-bonding behavior was identified at approximately 10% wood moisture content. Below this threshold, water was found to predominantly engage in strong hydrogen bonds within wood cell walls. Above 10% moisture content, the relative contribution of strong hydrogen bonds to the overall wood- water hydrogen bond network decreased, whereas weakly hydrogen-bonded population became increasingly dominant. Experiments on modified wood and isolated polymers indicated that this transition originates mainly from wood polysaccharides, while lignin plays a minor role. These findings provide strong evidence for distinct water populations in wood cell walls, distinguished by their intermolecular hydrogen-bonding energies and predominant at specific wood moisture contents
Ključne besede: infrared spectroscopy, wood-water interactions, hydrogen bonding, wood cell wall, cellulose
Objavljeno v RUP: 05.06.2026; Ogledov: 150; Prenosov: 9
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Multi-sensor and multi-way analysis of modified wood in service
Anna Malgorzata Sandak, Jakub Michal Sandak, Marina Cocchi, 2019, objavljeni znanstveni prispevek na konferenci

Ključne besede: modified wood, near infrared spectral data
Objavljeno v RUP: 11.02.2020; Ogledov: 3247; Prenosov: 50
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