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Title:Evaluation of the effectiveness of black tea leaves wastes as phytochemical-rich plant fillers and natural antioxidant in polyethylene
Authors:ID Aniśko-Michalak, Joanna (Author)
ID Sandak, Jakub Michal (Author)
ID Hejna, Aleksander (Author)
ID Barczewski, Mateusz (Author)
Files:.pdf RAZ_Aniśko-Michalak_Joanna_2026.pdf (2,03 MB)
MD5: E8A679D73B2388EF24ABF71A8665D358
 
URL https://www.degruyterbrill.com/document/doi/10.1515/epoly-2025-0099/html?utm_source=researchgate.net&utm_medium=article
 
Language:English
Work type:Article
Typology:1.01 - Original Scientific Article
Organization:IAM - Andrej Marušič Institute
Abstract:The aim of this study is to compare the structure as well as the mechanical and thermomechanical properties of polyethylene stabilized with a petrochemical additive (Irganox 1010) and a sustainable alternative, antioxidant-rich black tea waste leaves (BTW). The influence of both stabilizers was evaluated for samples produced by compression, injection, and rotational molding (CM, INM, and RM). The polymer ma- trix used was low-density polyethylene LDPE SBC 818 I’m Green® (Braskem), modified with 5 wt% BTW and an equiva- lent amount of Irganox 1010 based on the total phenolic con- tent in BTW. Stabilization efficiency was assessed using Fourier transform infrared spectroscopy (FTIR) and calori- metric techniques, including oxidation induction time (OIT) and oxidation onset temperature (OOT), both measured by differential scanning calorimetry (DSC). Additionally, porosity, mechanical performance in static tensile testing, and Vicat softening temperature (VST) were determined to provide a comprehensive comparison of the stabilization systems.
Keywords:polyethylene, thermoplastics, antioxidants, rotational molding, stabilization
Publication version:Version of Record
Publication date:15.04.2026
Year of publishing:2026
Number of pages:str. 1-12
Numbering:Vol. 26, iss. 1, [article no.] 20250099
PID:20.500.12556/RUP-23096 This link opens in a new window
UDC:678.742.2:678.048
ISSN on article:1618-7229
DOI:10.1515/epoly-2025-0099 This link opens in a new window
COBISS.SI-ID:280194819 This link opens in a new window
Publication date in RUP:02.06.2026
Views:36
Downloads:2
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Record is a part of a journal

Title:E-polymers
Publisher:B. Jung
ISSN:1618-7229
COBISS.SI-ID:2553882 This link opens in a new window

Document is financed by a project

Funder:ARIS - Slovenian Research and Innovation Agency
Project number:N4-0274-2023
Name:DENDRO-SPEC: Spektroskopske Metode za Hitro Fenotipizacijo Dreves, ki Odražajo Njihovo Ekološko Odpornost

Licences

License:CC BY 4.0, Creative Commons Attribution 4.0 International
Link:http://creativecommons.org/licenses/by/4.0/
Description:This is the standard Creative Commons license that gives others maximum freedom to do what they want with the work as long as they credit the author.

Secondary language

Language:Slovenian
Abstract:Cilj te študije je primerjati strukturo ter mehanske in termomehanske lastnosti polietilena, stabiliziranega s petrokemičnim dodatkom (Irganox 1010) in trajnostno alternativo – odpadnimi listi črnega čaja (BTW), bogatimi z antioksidanti. Vpliv obeh stabilizatorjev je bil ocenjen na vzorcih, izdelanih s kompresijskim, injekcijskim in rotacijskim oblikovanjem (CM, INM in RM). Kot polimerna matrica je bil uporabljen nizkogostotni polietilen LDPE SBC 818 I’m Green® (Braskem), modificiran s 5 mas. % BTW ter z ekvivalentno količino Irganoxa 1010 glede na skupno vsebnost fenolnih spojin v BTW. Učinkovitost stabilizacije je bila ocenjena s Fourierjevo transformacijsko infrardečo spektroskopijo (FTIR) in kalorimetričnimi metodami, vključno s časom indukcije oksidacije (OIT) in temperaturo začetka oksidacije (OOT), ki sta bila izmerjena z diferencialno dinamično kalorimetrijo (DSC). Poleg tega so bili določeni poroznost, mehanske lastnosti pri statičnem nateznem preskusu ter Vicatova temperatura zmehčanja (VST), da bi zagotovili celovito primerjavo obeh stabilizacijskih sistemov.
Keywords:polietilen, termoplastika, antioksidanti, rotacijsko brizganje, stabilizacija


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