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Naslov:Interlaboratory study of automated sorption measurements in wood : method for correcting systematic errors with the commonly used 0.002% min[sup] -1 stop criterion
Avtorji:ID Zelinka, Samuel L. (Avtor)
ID Glass, Samuel V. (Avtor)
ID Farkas, Natalia (Avtor)
ID Thybring, Emil Engelund (Avtor)
ID Altgen, Michael (Avtor)
ID Rautkari, Lauri (Avtor)
ID Curling, Simon F. (Avtor)
ID Cao, Jinzhen (Avtor)
ID Wang, Yujiao (Avtor)
ID Künniger, Tina (Avtor)
ID Schwarzkopf, Matthew (Avtor)
Datoteke:.pdf RAZ_Zelinka_Samuel_L._2025.pdf (3,09 MB)
MD5: 0A0B579789810AB93810B7F28B5DB849
 
URL https://link.springer.com/article/10.1007/s10450-025-00655-y
 
Jezik:Angleški jezik
Vrsta gradiva:Članek v reviji
Tipologija:1.01 - Izvirni znanstveni članek
Organizacija:IAM - Inštitut Andrej Marušič
Opis:Many studies that use an automated sorption balance to determine a water vapor sorption isotherm for wood collect data until the moisture content change is less than or equal to 0.002% min−1 (20 µg g−1 min−1). This stop criterion has been claimed to give errors in equilibrium moisture content (EMC) predictions of less than 0.001 g g−1 but over the past 10 years, studies have shown that the actual errors can be greater than 0.01 g g−1 because the measurements are stopped well before equilibrium is reached. Despite the large errors associated with this stop criterion, it remains popular due to the speed at which isotherms can be measured. This paper utilizes data from a worldwide interlaboratory study on automated sorption balances to develop a correction method for estimating EMC of western larch (Larix occidentalis Nutt.) from the moisture content corresponding to the 20 µg g−1 min−1 criterion. The study uses data from 72 relative humidity absorption steps with hold times of 7–10 days from 21 different laboratories and eight different instrument models. EMC is defined based on the inherent mass stability of automated sorption balances determined in the first part of this interlaboratory study. On average the sorption process is less than 80% complete when the 20 µg g−1 min−1 criterion is reached, resulting in a mean absolute error (MAE) of 0.006 g g−1. The correction equation for estimating EMC reduces the MAE to 0.001 g g−1. The analysis presented in this paper, along with the correction equation, can be considered for certain use cases to reduce systematic errors and shorten measurement times.
Ključne besede:water vapor sorption, dynamic vapor sorption, sorption isotherms, equilibrium moisture content, interlaboratory study
Datum objave:04.10.2025
Leto izida:2025
Št. strani:str. 1-21
Številčenje:Vol. 31, iss. 7, article no. 99
PID:20.500.12556/RUP-22116 Povezava se odpre v novem oknu
UDK:66
ISSN pri članku:0929-5607
DOI:10.1007/s10450-025-00655-y Povezava se odpre v novem oknu
COBISS.SI-ID:257252611 Povezava se odpre v novem oknu
Datum objave v RUP:14.11.2025
Število ogledov:284
Število prenosov:3
Metapodatki:XML DC-XML DC-RDF
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Gradivo je del revije

Naslov:Adsorption
Skrajšan naslov:Adsorption
Založnik:Kluwer Academic Publishers
ISSN:0929-5607
COBISS.SI-ID:512512025 Povezava se odpre v novem oknu

Licence

Licenca:CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
Povezava:http://creativecommons.org/licenses/by/4.0/deed.sl
Opis:To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.

Sekundarni jezik

Jezik:Slovenski jezik
Ključne besede:sorpcija vodne pare, dinamična sorpcija pare, sorpcijske izoterme, ravnotežna vsebnost vlage, medlaboratorijska študija


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